Information below was gathered using the actual videos of the movies. In the instances where I don't have a copy of the movie, information was gathered from the Internet Movie Database. Pierce Brosnan is listed as the first cast member on each film, even if he wasn't the first one in the credits. (Hey, I'm a fan of him...not these other people.)

DON'T TALK TO STRANGERS (1994)
An ex-husband doesn't trust his ex-wife's new boyfriend (Brosnan).
Directed by: Robert Michael Lewis
Written by: Jon George, Neill D. Hicks, Nevin Schreiner
Cast: Pierce Brosnan; Shanna Reed; Terry O'Quinn; Keegan MacIntosh; Michael MacRae; Roger R. Cross; Alan Robertson; Ken Roberts; Douglas Stewart; David Hirtubise; Dave 'Squatch' Ward; Colleen Winton; Meredith Bain Woodward; William B. Davis; Peter Hanlon; Tom Picket; Alf Humphreys; Tom Shorthouse; Dan Muldoon; Andrew McIlroy

LOVE AFFAIR (1994)
Two people, who are already involved with other people, meet and fall in love. Brosnan plays Bening's former boyfriend.
Directed by: Glenn Gordon Caron
Written by: Warren Beatty, Mildred Cram, Delmer Daves, Leo McCarey, Donald Ogden Stewart, Robert Towne
Cast: Pierce Brosnan; Warren Beatty; Annette Bening; Katharine Hepburn; Garry Shandling; Chloe Webb; Kate Capshaw; Paul Mazursky; Brenda Vaccaro; Glenn Shadix; Barry Miller; Harold Ramis; Linda Wallem; Meagen Fay; Ray Girardin; John Hostetter; Elya Baskin; Boris Lee Krutonog; Savely Kramarov; Oleg Vidov; Taylor Dayne; Carey Lowell; Ed McMahon; Dan Castellaneta; Jeffrey Nordling; Rosalind Chao; Rebecca Miller; Tom Signorelli; Cylk Cozart; Robert Levine; Frank Campanella; Wendie Jo Sperber; McNally Segal; Gary McGurk; Helena Carroll; Manu Tupou; Irene Olga López; Lisa Edelstein; Stefan Lysenko; Marek Probosz; Sergei Brusilovsky; Herman Sinitzyn; Rosalind Allen; James Pyduck; Jack Johnson; Lori Sebourn; Michael Gordon Bennett; Michael Fischetti; Michael F. Boyle; Mary Hart; John Tesh; Steve Kmetko; Terry Murphy; Barry Nolan; Andrea Kutyas; Ray Charles