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Electromagnetic Radiation |
Forms
of electromagnetic radiation
Ultraviolet Radiation
The German physicist Johann Wilhelm
Ritter, having learned of Herschel's discovery of infrared waves, looked
beyond the violet end of the visible spectrum of the Sun and found (in 1801)
that there exist invisible rays that darken silver chloride even more
efficiently than visible light. This spectral region extending between
visible light and X rays is designated ultraviolet. Sources of this form of
electromagnetic radiation are hot objects like the Sun, synchrotron
radiation sources, mercury or xenon arc lamps, and gaseous discharge tubes
filled with gas atoms (e.g., mercury, deuterium, or hydrogen) that have
internal electron energy levels which correspond to the photons of
ultraviolet light.
When ultraviolet light strikes certain materials, it causes them to
fluoresce--i.e., they emit electromagnetic radiation of lower energy, such
as visible light. The spectrum of fluorescent light is characteristic of a
material's composition and thus can be used for screening minerals,
detecting bacteria in spoiled food, identifying pigments, or detecting
forgeries of artworks and other objects (the aged surfaces of ancient marble
sculptures, for instance, fluoresce yellow-green, whereas a freshly cut
marble surface fluoresces bright violet).
Optical instruments for the
ultraviolet region are made of special materials, such as quartz, certain
silicates, and metal fluorides, which are transparent at least in the near
ultraviolet. Far-ultraviolet radiation is absorbed by nearly all gases and
materials and thus requires reflection optics in vacuum chambers.
Ultraviolet radiation is detected by
photographic plates and by means of the photoelectric effect in
photomultiplier tubes. Also, ultraviolet radiation can be converted to
visible light by fluorescence before detection.
The relatively high energy of
ultraviolet light gives rise to certain photochemical reactions. This
characteristic is exploited to produce cyanotype impressions on fabrics and
for blueprinting design drawings. Here, the fabric or paper is treated with
a mixture of chemicals that react upon exposure to ultraviolet light to form
an insoluble blue compound. Electronic excitations caused by ultraviolet
radiation also produce changes in the colour and transparency of
photosensitive and photochromic glasses. Photochemical and photostructural
changes in certain polymers constitute the basis for photolithography and
the processing of the microelectronic circuits.
Although invisible to the eyes of
humans and most vertebrates, near-ultraviolet light can be seen by many
insects. Butterflies and many flowers that appear to have identical colour
patterns under visible light are distinctly different when viewed under the
ultraviolet rays perceptible to insects.
An important difference between
ultraviolet light and electromagnetic radiation of lower frequencies is the
ability of the former to ionize, meaning that it can knock an electron out
from atoms and molecules. All high-frequency electromagnetic radiation
beyond the visible--i.e., ultraviolet light, X rays, and gamma rays--is
ionizing and therefore harmful to body tissues, living cells, and DNA
(deoxyribonucleic acid). The harmful effects of ultraviolet light to humans
and larger animals are mitigated by the fact that this form of radiation
does not penetrate much further than the skin.
The body of a sunbather is struck by
1021 photons every second, and 1 percent of these, or more than a billion
billion per second, are photons of ultraviolet radiation. Tanning and
natural body pigments help to protect the skin to some degree, preventing
the destruction of skin cells by ultraviolet light. Nevertheless,
overexposure to the ultraviolet component of sunlight can cause skin cancer,
cataracts of the eyes, and damage to the body's immune system. Fortunately a
layer of ozone (O3) in the stratosphere absorbs the most damaging
ultraviolet rays, which have wavelengths of 2000 and 2900 angstroms (one
angstrom [Å] = 10-10 metre), and attenuates those with wavelengths between
2900 and 3150 Å. Without this protective layer of ozone, life on Earth would
not be possible. The ozone layer is produced at an altitude of about 10 to
50 kilometres above the Earth's surface by a reaction between
upward-diffusing molecular oxygen (O2) and downward-diffusing ionized atomic
oxygen (O+). Many scientists believe that this life-protecting stratospheric
ozone layer is being reduced by chlorine atoms in chlorofluorocarbon (or
Freon) gases released into the atmosphere by aerosol propellants,
air-conditioner coolants, solvents used in the manufacture of electronic
components, and other sources. (For more specific information, see
atmosphere.)
Ionized atomic oxygen, nitrogen, and
nitric oxide are produced in the upper atmosphere by absorption of solar
ultraviolet radiation. This ionized region is the ionosphere, which affects
radio communications and reflects and absorbs radio waves of frequencies
below 40 MHz.
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