N.C.A.A. Division I National Champions
Women's Outdoor 100-Meter Hurdles
| Year | Name | School | Performance |
| 2011 | Nia Ali | Southern California | 12.63 |
| 2010 | Queen Harrison | Virginia Tech | 12.67 |
| 2009 | Tiffany Ofili | Michigan | 12.96 |
| 2008 | Tiffany Ofili | Michigan | 12.84 |
| 2007 | Tiffany Ofili | Michigan | 12.80 |
| 2006 | Virginia Powell | Southern California | 12.48 |
| 2005 | Virginia Powell | Southern California | 12.80 |
| 2004 | Nichole Denby | Texas | 12.62 |
| 2003 | Perdita Felicien | Illinois | 12.74 |
| 2002 | Perdita Felicien | Illinois | 12.91 |
| 2001 | Donica Merriman | Ohio State | 12.73 |
| 2000 | Joyce Bates | Louisiana State | 12.85 |
| 1999 | Yolanda McCray | Miami (Florida) | 12.85 |
| 1998 | Angie Vaughn | Texas | 12.82 |
| 1997 | Astia Walker | Louisiana State | 12.85 |
| 1996 | Kim Carson | Louisiana State | 12.82 |
| 1995 | Gillian Russell | Miami (Florida) | 12.99 |
| 1994 | Gillian Russell | Miami (Florida) | 12.97 |
| 1993 | Gillian Russell | Miami (Florida) | 13.02 |
| 1992 | Michelle Freeman | Florida | 12.90 |
| 1991 | Dawn Bowles | Louisian State | 12.70 |
| 1990 | Lynda Tolbert | Arizona State | 12.84 |
| 1989 | Tananjalyn Stanley | Louisiana State | 12.70 |
| 1988 | Lynda Tolbert | Arizona State | 12.82 |
| 1987 | LaVonna Martin | Tennessee | 13.05 |
| 1986 | Rosalind Pendegraft-Council | Auburn | 13.03 |
| 1985 | Rhonda Blandford | Nebraska | 12.70 |
| 1984 | Kim Turner | Texas-El Paso | 13.02 |
| 1983 | Benita Fitzgerald | Tennessee | 12.84 |
| 1982 | Benita Fitzgerald | Tennessee | 13.13 |
