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The Realm of The RPG

Chocomog
MP needed to cast: 14
Elemental: Wind
Obtained: Go to chocobo farm and talk to the chocobo on the left of the paddock looking over the fence.

Shiva
MP needed to cast: 32
Elemental: Ice
Obtained: Given to you by Priscilla after you save her from the giant fish in Junon.

Ifrit
MP needed to cast: 34
Elemental: Fire
Obtained: On the floor of the cargo ship after defeating Jenova Birth.

Ramuh
MP needed to cast: 40
Elemental: Lightning
Obtained: In the waiting room at the chocobo races (when you are racing to leave Corel Prison).

Titan
MP needed to cast: 46
Elemental: Earth
Obtained: Found at the destroyed reactor in Gongaga.

Odin
MP needed to cast: 80
Elemental: Non-Elemental
Obtained: You get this materia after defeating the boss in the safe in Nibelheim (The combination is Right 36, Left 10, Right 59, Right 97).

Leviathan
MP needed to cast: 78
Elemental: Water
Obtained: Go to the Pagoda in Wutai with Yuffie in your party and complete the mini quest.

Bahamut
MP needed to cast: 100
Elemental: Non-Elemental
Obtained: After defeating the Red Dragon in the Temple of the Ancients.

Kjata
MP needed to cast: 110
Elemental: Fire, Ice and Lightning
Obtained: In the sleeping forest

Alexander
MP needed to cast: 120
Elemental: Holy
Obtained: Found in Great Glacier.

Phoenix
MP needed to cast: 180
Elemental: Fire
Obtained: After winning the battle at Fort Condor.

Neo Bahamut
MP needed to cast: 140
Elemental: Non-Elemental
Obtained: Lying on the ground in the whirlwind maze.

Hades
MP needed to cast: 150
Elemental: Non-Elemental
Obtained: Found in the sunken Gelinka cargo plane.

Typoon
MP needed to cast: 160
Elemental: Wind
Obtained: In Frog Forest in the trees to the very right of the forest.

Bahamut ZERO
MP needed to cast: 180
Elemental: Non-Elemental
Obtained: After you bring all four Huge Materia to Bugenhagen, he will store it in his observatory and you can go look at it. If you have the Bahamut and Neo Bahamut materia with you, go to the Blue Huge Materia. It'll give you the Bahamut ZERO materia.

Knights of Round
MP needed to cast: 250
Elemental: Non-Elemental
Obtained: Found in the Materia Cave located on a round island in the upper right corner of the World Map.