Analyzing Alcohol
with
Infrared Spectroscopy

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The Sobriety Test

THE ANALYTE: Breath (suspected to contain alcohol)

THE IDENTITY TEST: The breath is tested with a mechanism similar to a breathalyzer. The diffference is that a breathalyzer relies on chemical oxidation, and therefore requires a dangerous reangent, while a mechanism using an IR test (for example, a CMI INTOXILIZER), uses the unique response of alcohol to infrared radiation.

Different compounds within alcohol (and other substances) resonate and absorb radiation only at specific wavelengths. The intoxilizer or other IR mechanism compares the resonance and absorption of infrared radiation from the breath in one chamber to the same properties in a second chamber, which contains air.

THE IDENTITY AND THE CRIME: An officer pulls over a driver who is breaking the speed limit. Suspecting the driver of being intoxicated, the officer tests the driver's breath with an intoxilizer, which gives the officer immediate result. Finding that the driver is under the influence of alcohol and is over the legal limit of alcohol. The officer suspends the driver's license, and the driver is ticketed and fined for driving under the influence of alcohol and putting other drivers and passengers at risk.

Source: White, P. (Ed.). (1998). Crime Scene to Court: The Essentials of Forensic Science. Cambridge, UK: Royal Society of Chemistry.
Photo from Eden Prairie Police Website


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